Research & Analysis
TAN Qi, GU Zhongyan, ZHANG Songwen, ZHOU Hao, GUO Derui, WANG Qingfeng, CHEN Xin
In order to explore the influence of type Ⅰ and type Ⅱ boundaries in the weld of TP347H/12Cr1MoV dissimilar metal welded joint after high temperature aging treatment on the microstructure and properties of the joint, CALPHAD method was employed, and Thermo-Calc software was utilized to study the equilibrium phase composition and precipitate behavior of the welded joints. The simulation results from Thermo-Calc software indicate that, under the same temperature at 600-800 ℃, the carbon activity in each alloy decreases in the order of 12Cr1MoV, weld, and TP347H. Considering the activity factor, the direction of carbon migration is from 12Cr1MoV to the weld at first and then to TP347H, which is consistent with the actual results of carbon migration. Additionally, the TP347H/12Cr1MoV welded joint was subjected to isothermal aging treatment at 650 ℃ for 1 500 h, then the microstructures and precipitate characteristics of type Ⅰ and type Ⅱ boundaries were analysed using metallographic microstructure observation, scanning electron microscopy, and energy dispersive spectroscopy. Results show that, the weld microstructure consists of a mixture of cellular and dendritic crystals. The solidification mode of the weld in the TP347H/12Cr1MoV welded joint is primarily the austenitic A-type solidification mode. After aging treatment, Cr-rich and Nb-rich phases appear in type Ⅰ and type Ⅱ boundaries of TP347H and weld interface.